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doi:10.22028/D291-33244 | Title: | Stereoselective Allylic Alkylations of Amino Ketones and Their Application in the Synthesis of Highly Functionalized Piperidines |
| Author(s): | Prudel, Cynthia Huwig, Kai Kazmaier, Uli |
| Language: | English |
| Title: | Chemistry - A European Journal |
| Volume: | 26 |
| Issue: | 14 |
| Pages: | 3181-3188 |
| Publisher/Platform: | Wiley |
| Year of Publication: | 2020 |
| Free key words: | allylic alkylation chelates enolates ketones palladium piperidines |
| DDC notations: | 500 Science 540 Chemistry 600 Technology |
| Publikation type: | Journal Article |
| Abstract: | Chelated ketone enolates are excellent nucleophiles for allylic alkylations. Electron-withdrawing groups on the allyl moiety allow subsequent intramolecular Michael additions giving rise to piperidines with up to five stereogenic centers. |
| DOI of the first publication: | 10.1002/chem.202000051 |
| Link to this record: | urn:nbn:de:bsz:291--ds-332441 hdl:20.500.11880/30595 http://dx.doi.org/10.22028/D291-33244 |
| ISSN: | 1521-3765 0947-6539 |
| Date of registration: | 9-Feb-2021 |
| Description of the related object: | Supporting Information |
| Related object: | https://chemistry-europe.onlinelibrary.wiley.com/action/downloadSupplement?doi=10.1002%2Fchem.202000051&file=chem202000051-sup-0001-misc_information.pdf |
| Faculty: | NT - Naturwissenschaftlich- Technische Fakultät |
| Department: | NT - Chemie |
| Professorship: | NT - Prof. Dr. Uli Kazmaier |
| Collections: | SciDok - Der Wissenschaftsserver der Universität des Saarlandes |
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| File | Description | Size | Format | |
|---|---|---|---|---|
| chem.202000051.pdf | 554,77 kB | Adobe PDF | View/Open |
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