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doi:10.22028/D291-43434 | Title: | Cross-Dehydrocoupling of Amines and Silanes Catalyzed by Magnesocenophanes |
| Author(s): | Wirtz, Lisa Lambert, Jessica Morgenstern, Bernd Schäfer, André |
| Language: | English |
| Title: | Organometallics |
| Volume: | 40 |
| Issue: | 13 |
| Pages: | 2108-2117 |
| Publisher/Platform: | ACS |
| Year of Publication: | 2021 |
| Free key words: | Amines Catalysis Catalysts Inorganic Compounds Magnesium |
| DDC notations: | 500 Science |
| Publikation type: | Journal Article |
| Abstract: | The application of C[1]magnesocenophanes in dehydrocoupling catalysis is reported. Two new cycloalkylidenebridged C[1]magnesocenophanes were synthesized and structurally characterized. These C[1]magnesocenophanes were used as catalysts in amine−borane dehydrocoupling and, more extensively, in amine−silane cross-dehydrocoupling. The substrate scope, involving different aliphatic, aromatic, and benzylic amines, was probed and the mechanism of this cross-dehydrocoupling catalysis was investigated. |
| DOI of the first publication: | 10.1021/acs.organomet.1c00245 |
| URL of the first publication: | https://pubs.acs.org/doi/10.1021/acs.organomet.1c00245 |
| Link to this record: | urn:nbn:de:bsz:291--ds-434349 hdl:20.500.11880/38941 http://dx.doi.org/10.22028/D291-43434 |
| ISSN: | 1520-6041 0276-7333 |
| Date of registration: | 13-Nov-2024 |
| Description of the related object: | Supporting Information |
| Related object: | https://pubs.acs.org/doi/suppl/10.1021/acs.organomet.1c00245/suppl_file/om1c00245_si_001.pdf https://pubs.acs.org/doi/suppl/10.1021/acs.organomet.1c00245/suppl_file/om1c00245_si_002.xyz |
| Faculty: | NT - Naturwissenschaftlich- Technische Fakultät |
| Department: | NT - Chemie |
| Professorship: | NT - Prof. Dr. Guido Kickelbick |
| Collections: | SciDok - Der Wissenschaftsserver der Universität des Saarlandes |
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