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doi:10.22028/D291-43387 | Title: | Application of Vinyl Nucleophiles in Matteson Homologations |
| Author(s): | Kinsinger, Thorsten Kazmaier, Uli |
| Language: | English |
| Title: | Organic Letters |
| Volume: | 24 |
| Issue: | 20 |
| Pages: | 3599-3603 |
| Publisher/Platform: | ACS |
| Year of Publication: | 2022 |
| Free key words: | Anions Chemical Reactions Organic Compounds Reagents Vinyl |
| DDC notations: | 500 Science |
| Publikation type: | Journal Article |
| Abstract: | The Matteson homologation with vinyl nucleophiles was found to be a versatile tool for the synthesis of highly substituted and functionalized allyl boronic esters. High yields and stereoselectivities are obtained with sterically demanding alkyl boronic esters and/or Grignard reagents. With the application of such vinyl Matteson homologations, the polyketide fragment of lagunamide B is synthesized. |
| DOI of the first publication: | 10.1021/acs.orglett.2c01119 |
| URL of the first publication: | https://pubs.acs.org/doi/10.1021/acs.orglett.2c01119 |
| Link to this record: | urn:nbn:de:bsz:291--ds-433878 hdl:20.500.11880/38907 http://dx.doi.org/10.22028/D291-43387 |
| ISSN: | 1523-7052 1523-7060 |
| Date of registration: | 7-Nov-2024 |
| Description of the related object: | Supporting Information |
| Related object: | https://pubs.acs.org/doi/suppl/10.1021/acs.orglett.2c01119/suppl_file/ol2c01119_si_001.pdf |
| Faculty: | NT - Naturwissenschaftlich- Technische Fakultät |
| Department: | NT - Chemie |
| Professorship: | NT - Prof. Dr. Uli Kazmaier |
| Collections: | SciDok - Der Wissenschaftsserver der Universität des Saarlandes |
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