Please use this identifier to cite or link to this item:
doi:10.22028/D291-41235
Title: | Swift C–C bond insertion by a 12-electron palladium(0) surrogate |
Author(s): | Breitwieser, Kevin Dankert, Fabian Grünwald, Annette Mayer, Paula R. Heinemann, Frank W. Munz, Dominik |
Language: | English |
Title: | Chemical Communications |
Volume: | 59 |
Issue: | 81 |
Pages: | 12104-12107 |
Publisher/Platform: | Royal Society of Chemistry |
Year of Publication: | 2023 |
DDC notations: | 500 Science |
Publikation type: | Journal Article |
Abstract: | The selective activation of C–C bonds holds vast promise for catalysis. So far, research has been primarily directed at rhodium and nickel under harsh reaction conditions. Herein, we report C–C insertion reactions of a 12-electron palladium(0) surrogate stabilized by a cyclic(alkyl)(amino) carbene (CAAC) ligand. Benzonitrile (1), biphenylene (2), benzocyclobutenone (3), and naphtho[b]cyclopropene (4) were studied. These substrates allow elucidation of the effect of ring strain as well as hybridization encompassing sp3 , sp2 and sp hybridized carbon atoms. All reactions proceed quantitatively at or below room temperature. This work therefore outlines perspectives for mild C–C bond functionalization catalysis. |
DOI of the first publication: | 10.1039/D3CC03964A |
URL of the first publication: | https://doi.org/10.1039/D3CC03964A |
Link to this record: | urn:nbn:de:bsz:291--ds-412355 hdl:20.500.11880/36984 http://dx.doi.org/10.22028/D291-41235 |
ISSN: | 1364-548X 1359-7345 |
Date of registration: | 28-Nov-2023 |
Sponsorship ID: | ERC(948185) |
Description of the related object: | Electronic supplementary information |
Related object: | https://www.rsc.org/suppdata/d3/cc/d3cc03964a/d3cc03964a1.pdf |
Faculty: | NT - Naturwissenschaftlich- Technische Fakultät |
Department: | NT - Chemie |
Professorship: | NT - Prof. Dr. Dominik Munz |
Collections: | SciDok - Der Wissenschaftsserver der Universität des Saarlandes |
Files for this record:
File | Description | Size | Format | |
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d3cc03964a.pdf | 1,86 MB | Adobe PDF | View/Open |
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