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doi:10.22028/D291-39033 | Title: | Matteson Homologation of Arylboronic Esters |
| Author(s): | Kinsinger, Thorsten Kazmaier, Uli |
| Language: | English |
| Title: | European Journal of Organic Chemistry |
| Volume: | 2022 |
| Issue: | 31 |
| Publisher/Platform: | Wiley |
| Year of Publication: | 2022 |
| Free key words: | Arylboronic esters Benzylic alcohols Epimerization Matteson homologation Stereoselective synthesis |
| DDC notations: | 500 Science |
| Publikation type: | Journal Article |
| Abstract: | Commercially available arylboronic acids can easily be converted into chiral boronic esters which can be subjected to Matteson homologations using Grignard reagents. The best results are obtained in one pot protocols without isolation of the α-chloroboronic ester intermediates. Alkoxides can also be used as nucleophiles, but the corresponding homologated boronic esters are found to be not stable. |
| DOI of the first publication: | 10.1002/ejoc.202200625 |
| URL of the first publication: | https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejoc.202200625 |
| Link to this record: | urn:nbn:de:bsz:291--ds-390335 hdl:20.500.11880/35205 http://dx.doi.org/10.22028/D291-39033 |
| ISSN: | 1099-0690 1434-193X |
| Date of registration: | 14-Feb-2023 |
| Faculty: | NT - Naturwissenschaftlich- Technische Fakultät |
| Department: | NT - Chemie |
| Professorship: | NT - Prof. Dr. Uli Kazmaier |
| Collections: | SciDok - Der Wissenschaftsserver der Universität des Saarlandes |
Files for this record:
| File | Description | Size | Format | |
|---|---|---|---|---|
| Eur J Org Chem - 2022 - Kinsinger - Matteson Homologation of Arylboronic Esters.pdf | 2,22 MB | Adobe PDF | View/Open |
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