Please use this identifier to cite or link to this item:
doi:10.22028/D291-38368 | Title: | A mesoionic carbene complex of manganese in five oxidation states |
| Author(s): | Wittwer, Benjamin Dickmann, Nicole Berg, Stephan Leitner, Daniel Tesi, Lorenzo Hunger, David Gratzl, Raphael van Slageren, Joris Neuman, Nicolas I. Munz, Dominik Hohloch, Stephan |
| Language: | English |
| Title: | Chemical Communications |
| Volume: | 58 |
| Issue: | 41 |
| Pages: | 6096–6099 |
| Publisher/Platform: | Royal Society of Chemistry |
| Year of Publication: | 2022 |
| DDC notations: | 500 Science |
| Publikation type: | Journal Article |
| Abstract: | Reaction between a carbazole-based mesoionic carbene ligand and manganese(II) iodide results in the formation of a rare air-stable manganese(IV) complex after aerobic workup. Cyclic voltammetry reveals the complex to be stable in five oxidation states. The electronic structure of all five oxidation states is elucidated chemically, spectroscopically (NMR, high-frequency EPR, UV-Vis, MCD), magnetically, and computationally (DFT, CASSCF). |
| DOI of the first publication: | 10.1039/D2CC00097K |
| URL of the first publication: | http://dx.doi.org/10.1039/d2cc00097k |
| Link to this record: | urn:nbn:de:bsz:291--ds-383681 hdl:20.500.11880/34611 http://dx.doi.org/10.22028/D291-38368 |
| ISSN: | 1364-548X 1359-7345 |
| Date of registration: | 2-Dec-2022 |
| Description of the related object: | Supplementary information |
| Related object: | https://www.rsc.org/suppdata/d2/cc/d2cc00097k/d2cc00097k1.pdf |
| Faculty: | NT - Naturwissenschaftlich- Technische Fakultät |
| Department: | NT - Chemie |
| Professorship: | NT - Prof. Dr. Dominik Munz |
| Collections: | SciDok - Der Wissenschaftsserver der Universität des Saarlandes |
Files for this record:
| File | Description | Size | Format | |
|---|---|---|---|---|
| d2cc00097k.pdf | 2,44 MB | Adobe PDF | View/Open |
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