Please use this identifier to cite or link to this item: doi:10.22028/D291-35450
Title: Setup of 4‐Prenylated Quinolines through Suzuki‐Miyaura Coupling for the Synthesis of Aurachins A and B
Author(s): Stief, Laura
Speicher, Andreas
Language: English
Title: Advanced Synthesis & Catalysis
Volume: 364
Issue: 1
Pages: 158–164
Publisher/Platform: Wiley
Year of Publication: 2021
Free key words: Aurachins
Suzuki-Miyaura coupling
Prenylated quinolines
Total synthesis
Natural product
DDC notations: 500 Science
Publikation type: Journal Article
Abstract: A polyprenyl side chain could be introduced into the heterocyclic quinoline moiety through Suzuki-Miyaura coupling of the corresponding quinoline-N-oxide with a polyprenyl boronic acid. This tool could be utilized for the synthesis of the natural product Aurachin B from the myxobacterium Stigmatella aurantiaca. This prenylated quinoline could then be transformed into the related Aurachin A through an epoxidation-ring opening cascade.
DOI of the first publication: 10.1002/adsc.202100884
Link to this record: urn:nbn:de:bsz:291--ds-354504
hdl:20.500.11880/32373
http://dx.doi.org/10.22028/D291-35450
ISSN: 1615-4169
1615-4150
Date of registration: 9-Feb-2022
Description of the related object: Supporting Information
Related object: https://onlinelibrary.wiley.com/action/downloadSupplement?doi=10.1002%2Fadsc.202100884&file=adsc202100884-sup-0001-misc_information.pdf
Faculty: NT - Naturwissenschaftlich- Technische Fakultät
Department: NT - Chemie
Professorship: NT - Keiner Professur zugeordnet
Collections:SciDok - Der Wissenschaftsserver der Universität des Saarlandes



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