Please use this identifier to cite or link to this item:
doi:10.22028/D291-35448 | Title: | Pentaisopropyl Cyclopentadienyl: An Overview across the Periodic Table |
| Author(s): | Lauk, Sergej Schäfer, André |
| Language: | English |
| Title: | European Journal of Inorganic Chemistry |
| Volume: | 2021 |
| Issue: | 48 |
| Pages: | 5026– 5036 |
| Publisher/Platform: | Wiley |
| Year of Publication: | 2021 |
| Free key words: | Cyclopentadienide Half-sandwich complexes Metallocenes Pentaisopropylcyclopentadienide Single molecule magnets |
| DDC notations: | 500 Science |
| Publikation type: | Journal Article |
| Abstract: | Cyclopentadienide (Cp) groups are among the most popular ligands in organometallic chemistry. Sterically demanding substitution patterns on the Cp ring can have an important effect on the ligand properties and there are many examples of metal complex which are only stable and isolatable with sterically demanding Cp ligands, carrying alkyl or aryl groups. Among these sterically demanding Cp ligands, pentaisopropylcyclopentadienide is the bulkiest pentaalkyl derivative and has been utilized in main group, as well as transition metal and rare-earth element chemistry for several decades. |
| DOI of the first publication: | 10.1002/ejic.202100770 |
| Link to this record: | urn:nbn:de:bsz:291--ds-354480 hdl:20.500.11880/32371 http://dx.doi.org/10.22028/D291-35448 |
| ISSN: | 1099-0682 1434-1948 |
| Date of registration: | 9-Feb-2022 |
| Faculty: | NT - Naturwissenschaftlich- Technische Fakultät |
| Department: | NT - Chemie |
| Professorship: | NT - Prof. Dr. Guido Kickelbick |
| Collections: | SciDok - Der Wissenschaftsserver der Universität des Saarlandes |
Files for this record:
| File | Description | Size | Format | |
|---|---|---|---|---|
| Euro J of Inorganic Chem - 2021 - Lauk - Pentaisopropyl Cyclopentadienyl An Overview across the Periodic Table.pdf | 4,12 MB | Adobe PDF | View/Open |
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