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doi:10.22028/D291-35444 | Title: | Diphosphanylmetallocenes of Main-Group Elements |
| Author(s): | Müller, Carsten Warken, Joshua Huch, Volker Morgenstern, Bernd Bischoff, Inga-Alexandra Zimmer, Michael Schäfer, André |
| Language: | English |
| Title: | Chemistry - A European Journal |
| Volume: | 27 |
| Issue: | 21 |
| Pages: | 6500 – 6510 |
| Publisher/Platform: | Wiley |
| Year of Publication: | 2021 |
| Free key words: | antimony group 14 heterobimetallic complexes magnesium metallocenes |
| DDC notations: | 500 Science |
| Publikation type: | Journal Article |
| Abstract: | Several 1,1’-diphosphanyl-substituted metallo cenes of magnesium (magnesocenes) were synthesized, structurally characterized, and their reactivity and coordina tion chemistry were investigated. Transmetalation of these magnesocenes gives access to group 14 metallocenes (tetre locenes), as well as to group 15 stibonocenes. These s- and p-block metallocenes represent a novel class of bis(phos phanyl) ligands, exhibiting Lewis-amphiphilic character. Their coordination chemistry towards different transition-metal and main-group fragments was investigated and different complexes are presented. |
| DOI of the first publication: | 10.1002/chem.202005198 |
| Link to this record: | urn:nbn:de:bsz:291--ds-354448 hdl:20.500.11880/32368 http://dx.doi.org/10.22028/D291-35444 |
| ISSN: | 1521-3765 0947-6539 |
| Date of registration: | 9-Feb-2022 |
| Description of the related object: | Supporting Information |
| Related object: | https://chemistry-europe.onlinelibrary.wiley.com/action/downloadSupplement?doi=10.1002%2Fchem.202005198&file=chem202005198-sup-0001-misc_information.pdf |
| Faculty: | NT - Naturwissenschaftlich- Technische Fakultät |
| Department: | NT - Chemie |
| Professorship: | NT - Prof. Dr. Guido Kickelbick |
| Collections: | SciDok - Der Wissenschaftsserver der Universität des Saarlandes |
Files for this record:
| File | Description | Size | Format | |
|---|---|---|---|---|
| Chemistry A European J - 2021 - M ller - Diphosphanylmetallocenes of Main‐Group Elements.pdf | 2,41 MB | Adobe PDF | View/Open |
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