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doi:10.22028/D291-23886 | Title: | Stannylene and germylene as powerful dechlorinated reagents : new route to diphosphene |
| Author(s): | Veith, Michael Huch, Volker Majoral, Jean-Pierre Bertrand, Guy Nanuel, Georges |
| Language: | English |
| Year of Publication: | 1983 |
| OPUS Source: | Tetrahedron letters. - 24. 1983, 39, S. 4219-4222 |
| SWD key words: | Phosphor-substituierte Verbindungen |
| DDC notations: | 540 Chemistry |
| Publikation type: | Journal Article |
| Abstract: | Dichlorophosphines RPCl2 [R=Cl ( ), Ph ( ) and 2,4,6-But3C6H2 ( ] are reduced to the corresponding phosphorus-I compounds by the stannylene Me2Si (NBut)2Sn: ( ) or by the germylene GeI2 ( ) ; in the case of the reaction of ( ) with ( , bis(2,4,6-tri-tert-butylphenyl)-diphosphene ( ) is obtained with a 65 % yield. |
| Link to this record: | urn:nbn:de:bsz:291-scidok-18898 hdl:20.500.11880/23942 http://dx.doi.org/10.22028/D291-23886 |
| Date of registration: | 8-Dec-2008 |
| Faculty: | SE - Sonstige Einrichtungen |
| Department: | SE - INM Leibniz-Institut für Neue Materialien |
| Collections: | INM SciDok - Der Wissenschaftsserver der Universität des Saarlandes |
Files for this record:
| File | Description | Size | Format | |
|---|---|---|---|---|
| ve198301.pdf | 153,37 kB | Adobe PDF | View/Open |
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