Please use this identifier to cite or link to this item: doi:10.22028/D291-23886
Title: Stannylene and germylene as powerful dechlorinated reagents : new route to diphosphene
Author(s): Veith, Michael
Huch, Volker
Majoral, Jean-Pierre
Bertrand, Guy
Nanuel, Georges
Language: English
Year of Publication: 1983
OPUS Source: Tetrahedron letters. - 24. 1983, 39, S. 4219-4222
SWD key words: Phosphor-substituierte Verbindungen
DDC notations: 540 Chemistry
Publikation type: Journal Article
Abstract: Dichlorophosphines RPCl2 [R=Cl ( ), Ph ( ) and 2,4,6-But3C6H2 ( ] are reduced to the corresponding phosphorus-I compounds by the stannylene Me2Si (NBut)2Sn: ( ) or by the germylene GeI2 ( ) ; in the case of the reaction of ( ) with ( , bis(2,4,6-tri-tert-butylphenyl)-diphosphene ( ) is obtained with a 65 % yield.
Link to this record: urn:nbn:de:bsz:291-scidok-18898
Date of registration: 8-Dec-2008
Faculty: SE - Sonstige Einrichtungen
Department: SE - INM Leibniz-Institut für Neue Materialien
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