Please use this identifier to cite or link to this item: doi:10.22028/D291-22562
Title: On the differing Lewis basicity of In(I) compared with Sn(II) in molecular indium-tin and thallium-tin alkoxides [Chemistry of alkoxystannates ; 6]
Author(s): Veith, Michael
Kunze, Klaus
Language: English
Year of Publication: 1991
OPUS Source: Angewandte Chemie / International edition in English. - 30. 1991, 1, S. 95-97
SWD key words: Indium-Indium-Bindung
DDC notations: 540 Chemistry
Publikation type: Journal Article
Abstract: A nearly linear arrangement of the four metal atoms Cr, Sn, In, and Mo, as well as an eclipsed arrangement of the [M(CO)5] fragments, in complex 1 was shown by X-ray structure analysis. Complex 1 was formed by successive addition of [M(CO)5 (thf)] to the bridgehead centers of Sn(OtBu)3In. The two centers differ in their basicity.
Link to this record: urn:nbn:de:bsz:291-scidok-18252
Date of registration: 19-Feb-2009
Faculty: NT - Naturwissenschaftlich- Technische Fakultät
Department: NT - Chemie
SE - INM Leibniz-Institut für Neue Materialien
Collections:SciDok - Der Wissenschaftsserver der Universität des Saarlandes

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