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doi:10.22028/D291-22306 | Title: | Introduction of oxygen-functions into the alpha position of ß-diketones, 8): Acyloxylation of copper(II) acetylacetonate with diacyl peroxides. |
| Author(s): | Schank, Kurt Beck, Horst |
| Other involved persons: | Heisel, Thomas |
| Language: | English |
| Year of Publication: | 1994 |
| OPUS Source: | Synthesis 1994 |
| Free key words: | Acyloxylierung Peroxydicarbonat Kupfer(II)-acetylacetonat Acyloxylation Peroxydicarbonates Copper(II) acetylacetonate |
| DDC notations: | 540 Chemistry |
| Publikation type: | Report |
| Abstract: | Replacement of only one hydrogen of the methylene group of 2.4-pentanedione (1) (acetylacetone) can be obtained by conversion of copper(II) acetylacetonate (2) with peroxydicarbonates 6 whereas dibenzoylperoxide (3) (DBPO) leads to geminal disubstitution. |
| Link to this record: | urn:nbn:de:bsz:291-scidok-193 hdl:20.500.11880/22362 http://dx.doi.org/10.22028/D291-22306 |
| Date of registration: | 29-Aug-2000 |
| Faculty: | NT - Naturwissenschaftlich- Technische Fakultät |
| Department: | NT - Chemie |
| Collections: | SciDok - Der Wissenschaftsserver der Universität des Saarlandes |
Files for this record:
| File | Description | Size | Format | |
|---|---|---|---|---|
| Introduction_oxygenfunctions8.pdf | 19,5 kB | Adobe PDF | View/Open |
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