Please use this identifier to cite or link to this item:
doi:10.22028/D291-22304 | Title: | Acyloxylation of 1-methoxycyclohex-1-ene and other enol ethers with dimethyl peroxydicarbonate |
| Author(s): | Schank, Kurt Beck, Horst Pistorius, Susanne Rapold, Thomas |
| Other involved persons: | Heisel, Thomas |
| Language: | English |
| Year of Publication: | 1995 |
| SWD key words: | Enolether |
| Free key words: | Acyloxylierung Dimethylperoxodicarbonat DPDC enolether acyloxylation dimethyl peroxydicarbonate DPDC |
| DDC notations: | 540 Chemistry |
| Publikation type: | Report |
| Abstract: | Acyloxylation of different types of enol ethers (derived from aldehydes and ketones) by dimethyl peroxydicarbonate (DPDC) results in either addition to the double bond or in a formal replacement of an allylic hydrogen by a methoxycarbonyloxy group forming vicinal oxygenated hydrocarbons. 1,3-oxygenated products via monoacyloxylation could not be observed. The results with 1-methoxycyclohex-1-ene (1a) are compared with copper(I)-salt catalyzed acyloxylations by means of tert. butyl peroxycarboxylates 2a, b. |
| Link to this record: | urn:nbn:de:bsz:291-scidok-129 hdl:20.500.11880/22360 http://dx.doi.org/10.22028/D291-22304 |
| Date of registration: | 15-Jun-2000 |
| Faculty: | NT - Naturwissenschaftlich- Technische Fakultät |
| Department: | NT - Chemie |
| Collections: | SciDok - Der Wissenschaftsserver der Universität des Saarlandes |
Files for this record:
| File | Description | Size | Format | |
|---|---|---|---|---|
| Acyloxylation_1-Methoxy_1-cyclohexene.pdf | 78,46 kB | Adobe PDF | View/Open |
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