Please use this identifier to cite or link to this item: doi:10.22028/D291-22304
Title: Acyloxylation of 1-methoxycyclohex-1-ene and other enol ethers with dimethyl peroxydicarbonate
Author(s): Schank, Kurt
Beck, Horst
Pistorius, Susanne
Rapold, Thomas
Other involved persons: Heisel, Thomas
Language: English
Year of Publication: 1995
SWD key words: Enolether
Free key words: Acyloxylierung
dimethyl peroxydicarbonate
DDC notations: 540 Chemistry
Publikation type: Report
Abstract: Acyloxylation of different types of enol ethers (derived from aldehydes and ketones) by dimethyl peroxydicarbonate (DPDC) results in either addition to the double bond or in a formal replacement of an allylic hydrogen by a methoxycarbonyloxy group forming vicinal oxygenated hydrocarbons. 1,3-oxygenated products via monoacyloxylation could not be observed. The results with 1-methoxycyclohex-1-ene (1a) are compared with copper(I)-salt catalyzed acyloxylations by means of tert. butyl peroxycarboxylates 2a, b.
Link to this record: urn:nbn:de:bsz:291-scidok-129
Date of registration: 15-Jun-2000
Faculty: NT - Naturwissenschaftlich- Technische Fakultät
Department: NT - Chemie
Collections:SciDok - Der Wissenschaftsserver der Universität des Saarlandes

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