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doi:10.22028/D291-35588
Titel: | History-Dependent Stress Relaxation of Liquids under High-Confinement: A Molecular Dynamics Study |
Alternativtitel: | Lubricants |
VerfasserIn: | Gao, Hongyu |
Sprache: | Englisch |
Titel: | Lubricants |
Bandnummer: | 10 |
Heft: | 2 |
Verlag/Plattform: | MDPI |
Erscheinungsjahr: | 2022 |
Freie Schlagwörter: | liquids confinement stress relaxation molecular dynamics hysteresis |
DDC-Sachgruppe: | 500 Naturwissenschaften |
Dokumenttyp: | Journalartikel / Zeitschriftenartikel |
Abstract: | When liquids are confined into a nanometer-scale slit, the induced layering-like film structure allows the liquid to sustain non-isotropic stresses and thus be load-bearing. Such anisotropic characteristics of liquid under confinement arise naturally from the liquids’ wavenumber dependent compressibility, which does not need solidification to take place as a prerequisite. In other words, liquids under confinement can still retain fluidity with molecules being (sub-)diffusive. However, the extensively prolonged structural relaxation times can cause hysteresis of stress relaxation of confined molecules in response to the motions of confining walls and thereby rendering the quasi-static stress tensors history-dependent. In this work, by means of molecular dynamics, stress tensors of a highly confined key base-oil component, i.e., 1-decene trimer, are calculated after its relaxation from being compressed and decompressed. A maximum of 77.1 MPa normal stress discrepancy has been detected within a triple-layer boundary film. Analyses with respect to molecular morphology indicate that among the effects (e.g., confinement, molecular structure, and film density) that can potentially affect confined stresses, the ordering status of the confined molecules plays a predominant role. |
DOI der Erstveröffentlichung: | 10.3390/lubricants10020015 |
Link zu diesem Datensatz: | urn:nbn:de:bsz:291--ds-355887 hdl:20.500.11880/32499 http://dx.doi.org/10.22028/D291-35588 |
ISSN: | 2075-4442 |
Datum des Eintrags: | 1-Mär-2022 |
Fakultät: | NT - Naturwissenschaftlich- Technische Fakultät |
Fachrichtung: | NT - Materialwissenschaft und Werkstofftechnik |
Professur: | NT - Keiner Professur zugeordnet |
Sammlung: | SciDok - Der Wissenschaftsserver der Universität des Saarlandes |
Dateien zu diesem Datensatz:
Datei | Beschreibung | Größe | Format | |
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lubricants-10-00015.pdf | 943,22 kB | Adobe PDF | Öffnen/Anzeigen |
Diese Ressource wurde unter folgender Copyright-Bestimmung veröffentlicht: Lizenz von Creative Commons