Please use this identifier to cite or link to this item: doi:10.22028/D291-33476
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Title: Particle encapsulation techniques for atom probe tomography of precipitates in microalloyed steels
Author(s): Webel, Johannes
Weber, Louis
Vardo, Emina
Britz, Dominik
Kraus, Tobias
Mücklich, Frank
Language: English
Title: Ultramicroscopy
Volume: 223
Publisher/Platform: Elsevier
Year of Publication: 2021
Publikation type: Journal Article
Abstract: Atom probe tomography (APT) provides sub-nm resolution in the analysis of complex industrial steels. It can resolve the carbonitride precipitates in Nb-Ti microalloyed high-strength low-alloy (HSLA) steels that strongly affect material performance and illuminate the complex precipitation sequence before and during the thermo-mechanical controlled process (TMCP). However, the precipitate concentration is low in HSLA steels during austenite conditioning, especially at temperatures > 850 °C, so that the probability of detecting precipitates via APT is below 5%. Here, we demonstrate two encapsulation-based approaches that increase the precipitate concentration in the APT sample volume sufficiently to enable the analysis of sparse precipitates. The first method is based on metallographic etching and direct targeting of precipitates in the steel. A focused ion beam was used to mark precipitation sites. Encapsulation with nickel-phosphorus (Ni-P) enabled localized APT and increased the yield by a factor of 10. The second method relies on the chemical extraction of precipitates and subsequent encapsulation in a silicon oxide (SiOx) network at a very high particle density. Analysis of tips cut from the encapsulated particles increased the yield by a factor of >15. We discuss and compare the spatial and chemical accuracy obtained in the analysis of pure Nb-, Ti- and mixed Nb-Ti carbonitrides.
DOI of the first publication: 10.1016/j.ultramic.2021.113219
URL of the first publication: https://www.sciencedirect.com/science/article/abs/pii/S0304399121000188
Link to this record: hdl:20.500.11880/30772
http://dx.doi.org/10.22028/D291-33476
ISSN: 1879-2723
0304-3991
Date of registration: 1-Mar-2021
Faculty: NT - Naturwissenschaftlich- Technische Fakultät
Department: NT - Chemie
Professorship: NT - Prof. Dr. Tobias Kraus
Collections:Die Universitätsbibliographie

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