Please use this identifier to cite or link to this item: doi:10.22028/D291-33183
Title: Donor-Stabilized Monocarba-Bridged Bis(cyclopentadienyl)alanes
Author(s): Haider, Wasim
Huch, Volker
Morgenstern, Bernd
Schäfer, André
Language: English
Title: ChemistryOpen
Volume: 9
Issue: 11
Pages: 1095-1099
Publisher/Platform: Wiley
Year of Publication: 2020
Free key words: aluminum
DDC notations: 500 Science
540 Chemistry
Publikation type: Journal Article
Abstract: Five monocarba-bridged bis(cyclopentadienyl)aluminum halide NHC and thione complexes and one monocarba-bridged bis(cyclopentadienyl)phosphanylalane NHC complex are reported. The former were synthesized by transmetalation of a C[1]magnesocenophane with the corresponding aluminum(III) chloride and aluminum(III) bromide donor adducts. The phosphanylalane complex was obtained by a subsequent functionalization of the corresponding bromoalane with lithium diphenylphosphide. All complexes were characterized in solution by multinuclear NMR spectroscopy and in the solid state by single crystal X-ray diffraction. Bonding energies of the NHC and thione ligands to the aluminum centres were estimated by DFT calculations.
DOI of the first publication: 10.1002/open.202000191
Link to this record: urn:nbn:de:bsz:291--ds-331833
ISSN: 2191-1363
Date of registration: 1-Feb-2021
Description of the related object: Supporting Information
Related object:
Faculty: NT - Naturwissenschaftlich- Technische Fakultät
Department: NT - Chemie
Professorship: NT - Keiner Professur zugeordnet
Collections:SciDok - Der Wissenschaftsserver der Universität des Saarlandes

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