Please use this identifier to cite or link to this item: doi:10.22028/D291-32431
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Title: Combining Battery‐Type and Pseudocapacitive Charge Storage in Ag/Ti3C2Tx MXene Electrode for Capturing Chloride Ions with High Capacitance and Fast Ion Transport
Author(s): Liang, Mingxing
Wang, Lei
Presser, Volker
Dai, Xiaohu
Yu, Fei
Ma, Jie
Language: English
Title: Advanced science
Volume: 7
Issue: 18
Startpage: 1
Endpage: 9
Publisher/Platform: Wiley
Year of Publication: 2020
Publikation type: Journal Article
Abstract: The recent advances in chloride‐ion capturing electrodes for capacitive deionization (CDI) are limited by the capacity, rate, and stability of desalination. This work introduces Ti3C2Tx/Ag synthesized via a facile oxidation‐reduction method and then uses it as an anode for chloride‐ion capture in CDI. Silver nanoparticles are formed successfully and uniformly distributed with the layered‐structure of Ti3C2Tx. All Ti3C2Tx/Ag samples are hydrophilic, which is beneficial for water desalination. Ti3C2Tx/Ag samples with a low charge transfer resistance exhibit both pseudocapacitive and battery behaviors. Herein, the Ti3C2Tx/Ag electrode with a reaction time of 3 h exhibits excellent desalination performance with a capacity of 135 mg Cl− g−1 at 20 mA g−1 in a 10 × 10−3 m NaCl solution. Furthermore, low energy consumption of 0.42 kWh kg−1 Cl− and a desalination rate of 1.5 mg Cl− g−1 min−1 at 50 mA g−1 is achieved. The Ti3C2Tx/Ag system exhibits fast rate capability, high desalination capacity, low energy consumption, and excellent cyclability, which can be ascribed to the synergistic effect between the battery and pseudocapacitive behaviors of the Ti3C2Tx/Ag hybrid material. This work provides fundamental insight into the coupling of battery and pseudocapacitive behaviors during Cl− capture for electrochemical desalination.
DOI of the first publication: 10.1002/advs.202000621
URL of the first publication: https://onlinelibrary.wiley.com/doi/full/10.1002/advs.202000621
Link to this record: hdl:20.500.11880/29814
http://dx.doi.org/10.22028/D291-32431
ISSN: 2198-3844
Date of registration: 6-Oct-2020
Faculty: NT - Naturwissenschaftlich- Technische Fakultät
Department: NT - Materialwissenschaft und Werkstofftechnik
Professorship: NT - Prof. Dr. Volker Presser
Collections:Die Universitätsbibliographie

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