Please use this identifier to cite or link to this item: doi:10.22028/D291-29771
Volltext verfügbar? / Dokumentlieferung
Title: H2-Generation from Alcohols by the MOF-Based Noble Metal-Free Photocatalyst Ni/CdS/TiO2@MIL-101
Author(s): Tilgner, Dominic
Klarner, Mara
Hammon, Sebastian
Friedrich, Martin
Verch, Andreas
de Jonge, Niels
Kümmel, Stephan
Kempe, Rhett
Language: English
Title: Australian Journal of Chemistry
Volume: 72
Issue: 10
Startpage: 842
Endpage: 847
Publisher/Platform: CSIRO Publishing
Year of Publication: 2019
Publikation type: Journal Article
Abstract: The synthesis of important classes of chemical compounds from alcohols helps to conserve Earth’s fossil carbon resources, since alcohols can be obtained from indigestible and abundantly available biomass. The utilisation of visible light for the activation of alcohols permits alcohol-based C–N and C–C bond formation under mild conditions inaccessible with thermally operating hydrogen liberation catalysts. Herein, we report on a noble metal-free photocatalyst able to split alcohols into hydrogen and carbonyl compounds under inert gas atmosphere without the requirement of electron donors, additives, or aqueous reaction media. The reusable photocatalyst mediates C–N multiple bond formation using the oxidation of alcohols and subsequent coupling with amines. The photocatalyst consists of a CdS/TiO2 heterojunction decorated with co-catalytic Ni nanoparticles and is prepared on size-optimised colloidal metal–organic framework (MOF) crystallites.
DOI of the first publication: 10.1071/CH19255
Link to this record: hdl:20.500.11880/28191
ISSN: 0004-9425
Date of registration: 25-Oct-2019
Faculty: NT - Naturwissenschaftlich- Technische Fakultät
Department: NT - Physik
Professorship: NT - Keiner Professur zugeordnet
Collections:Die Universitätsbibliographie

Files for this record:
There are no files associated with this item.

Items in SciDok are protected by copyright, with all rights reserved, unless otherwise indicated.