Please use this identifier to cite or link to this item: doi:10.22028/D291-29130
Volltext verfügbar? / Dokumentlieferung
Title: Ordered Mesoporous Titania/Carbon Hybrid Monoliths for Lithium-ion Battery Anodes with High Areal and Volumetric Capacity
Author(s): Dörr, Tobias S.
Fleischmann, Simon
Zeiger, Marco
Grobelsek, Ingrid
de Oliveira, Peter W.
Presser, Volker
Language: English
Title: Chemistry
Volume: 24
Issue: 24
Startpage: 6358
Endpage: 6363
Publisher/Platform: Wiley-Blackwell - STM
Year of Publication: 2018
Publikation type: Journal Article
Abstract: Free-standing, binder-free, and conductive additive-free mesoporous titanium dioxide/carbon hybrid electrodes were prepared from co-assembly of a poly(isoprene)-block-poly(styrene)-block-poly(ethylene oxide) block copolymer and a titanium alkoxide. By tailoring an optimized morphology, we prepared macroscopic mechanically stable 300 μm thick monoliths that were directly employed as lithium-ion battery electrodes. High areal mass loading of up to 26.4 mg cm-2 and a high bulk density of 0.88 g cm-3 were obtained. This resulted in a highly increased volumetric capacity of 155 mAh cm-3 , compared to cast thin film electrodes. Further, the areal capacity of 4.5 mAh cm-2 represented a 9-fold increase compared to conventionally cast electrodes. These attractive performance metrics are related to the superior electrolyte transport and shortened diffusion lengths provided by the interconnected mesoporous nature of the monolith material, assuring superior rate handling, even at high cycling rates.
DOI of the first publication: 10.1002/chem.201801099
Link to this record: hdl:20.500.11880/28055
http://dx.doi.org/10.22028/D291-29130
ISSN: 1521-3765
0947-6539
Date of registration: 10-Oct-2019
Faculty: NT - Naturwissenschaftlich- Technische Fakultät
Department: NT - Materialwissenschaft und Werkstofftechnik
Collections:UniBib – Die Universitätsbibliographie

Files for this record:
There are no files associated with this item.


Items in SciDok are protected by copyright, with all rights reserved, unless otherwise indicated.