Please use this identifier to cite or link to this item: doi:10.22028/D291-28901
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Title: Ordered Mesoporous Carbons with High Micropore Content and Tunable Structure Prepared by Combined Hard and Salt Templating as Electrode Materials in Electric Double-Layer Capacitors
Author(s): Yan, Runyu
Heil, Tobias
Presser, Volker
Walczak, Ralf
Antonietti, Markus
Oschatz, Martin
Language: English
Title: Advanced Sustainable Systems
Volume: 2
Issue: 2
Publisher/Platform: Wiley
Year of Publication: 2017
Publikation type: Journal Article
Abstract: Synthesis of high surface area carbon materials with hierarchical pore structure is reported. Combined salt templating with ZnCl2 and hard templating with SBA‐15 is used to produce ordered mesoporous and microporous hard–salt‐templated carbons (OM‐HSTCs) from simple sucrose as carbon precursor. OM‐HSTCs achieve specific surface areas of more than 2600 m2 g−1 and total pore volumes up to 2.2 cm3 g−1. In comparison to purely hard‐templated ordered mesoporous carbons, the additional salt template leads to high micropore volume and provides control over the size/distribution of micro‐ and mesopores and over the carbon microstructure. This method combines carbonization and the formation of well‐defined micropores in one step and is more versatile in terms of resulting pore structure than previously reported routes toward ordered mesoporous/microporous carbons. When applied as electrode materials in electric double‐layer capacitors with 1 m tetraethylammonium tetrafluoroborate in acetonitrile organic electrolyte, OM‐HSTCs combine high gravimetric capacitance (133 F g−1 at 0.1 A g−1) resulting from high micropore volume with high capacitance retention under high‐power conditions (126 F g−1 at 40 A g−1), exceeding the purely microporous or purely ordered mesoporous reference materials.
DOI of the first publication: 10.1002/adsu.201700128
URL of the first publication: https://onlinelibrary.wiley.com/doi/full/10.1002/adsu.201700128
Link to this record: hdl:20.500.11880/27808
http://dx.doi.org/10.22028/D291-28901
ISSN: 2366-7486
Date of registration: 17-Sep-2019
Faculty: NT - Naturwissenschaftlich- Technische Fakultät
Department: NT - Materialwissenschaft und Werkstofftechnik
Professorship: NT - Prof. Dr. Volker Presser
Collections:UniBib – Die Universitätsbibliographie

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