Please use this identifier to cite or link to this item: doi:10.22028/D291-28795
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Title: Gyroidal Niobium Sulfide/Carbon Hybrid Monoliths for Electrochemical Energy Storage
Author(s): Fleischmann, Simon
Dörr, Tobias S.
Frank, Anna
Hieke, Stefan W.
Doblas‐Jimenez, David
Scheu, Christina
de Oliveira, Peter W.
Kraus, Tobias
Presser, Volker
Language: English
Title: Batteries & Supercaps
Volume: 2
Issue: 8
Startpage: 668
Endpage: 672
Publisher/Platform: Wiley-VCH Verlag
Year of Publication: 2019
Publikation type: Journal Article
Abstract: Transition metal dichalcogenides are attractive two‐dimensional electrode materials for electrochemical energy storage devices due to their high reversible charge storage capacity. Hybridization of these materials with carbon promises enhanced performance by facilitating the access to reactive sites and extended mechanical stabilization. Herein, we introduce a NbS2/C hybrid material exhibiting a gyroidal microstructure synthesized through macromolecular co‐assembly of a tailored block copolymer and an organometallic niobium precursor and subsequent sulfidation. Our synthesis allows the preparation of mechanically stable monoliths with NbS2 nanocrystals engulfed in a highly porous carbon shell. Due to the curvature of the gyroidal structure, abundant reactive sites are exposed that lead to an attractive performance in a lithium‐containing electrolyte with a capacity of up to 400 mAh/g.
DOI of the first publication: 10.1002/batt.201900035
URL of the first publication: https://onlinelibrary.wiley.com/doi/epdf/10.1002/batt.201900035
Link to this record: hdl:20.500.11880/27747
http://dx.doi.org/10.22028/D291-28795
ISSN: 2566-6223
2566-6223
Date of registration: 10-Sep-2019
Faculty: NT - Naturwissenschaftlich- Technische Fakultät
Department: NT - Chemie
NT - Materialwissenschaft und Werkstofftechnik
Collections:UniBib – Die Universitätsbibliographie

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