Please use this identifier to cite or link to this item: doi:10.22028/D291-24504
Title: 29Si NMR investigation of condensation reactions of diphenylsilanediol in presence of Ti-, Zr-, Al-, Sn- and Si-alkoxides
Author(s): Hoebbel, Dagobert
Reinert, Thomas
Schmidt, Helmut K.
Language: English
Year of Publication: 1996
OPUS Source: Journal of sol gel science and technology. - 7. 1996, 3, S. 217-224
SWD key words: Metall
DDC notations: 620 Engineering and machine engineering
Publikation type: Journal Article
Abstract: The investigation of the effects of small amounts of Ti-, Zr-, Al-, Sn- and Si-alkoxides and those of triethylamine and hydrochloric acid on the condensation reaction of diphenylsiloxanediol (DPSD) in molar ratio Si : additive = 1:0.01 and 1:0.04 by 29Si NMR shows a decrease in their activity in the order Ti ≈ HCl > Al > Sn ≈ N(Et)3 ≈ Zr > Si after 6 h reaction time. The influence of the type of alkoxide ligands attached to the metal on the condensation rate of DPSD was found relatively low compared to the different metals. In presence of Ti-alkoxide the condensation reaction of DPSD leads to di-, tri- and tetrasiloxanediols, the latter of which dominates and crystallizes from the solution as octaphenyltetrasiloxanediol. The catalysis of DPSD solutions by Al-alkoxide and HCl results preferably in tetraphenyldisiloxanediol species even after a few days. The complexity of metal alkoxides and the hydrolytic stability of heterometallic Si - O - M bonds have been discussed as possible reasons for the differences in the catalytic activity of the metal alkoxide.
Link to this record: urn:nbn:de:bsz:291-scidok-28151
Date of registration: 26-Mar-2010
Faculty: SE - Sonstige Einrichtungen
Department: SE - INM Leibniz-Institut für Neue Materialien
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