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Titel: Grey, brown and blue coloring sol-gel electrochromic devices
Verfasser: Heusing, Sabine
Sun, Donglan L.
Otero-Anaya, J.
Aegerter, Michel A.
Sprache: Englisch
Erscheinungsjahr: 2006
Quelle: Thin solid films. - 502. 2006, 1-2, S. 240-245
SWD-Schlagwörter: Elektrochromie
Niob
Oxide
Wassergehalt
Kristallinität
DDC-Sachgruppe: 620 Ingenieurwissenschaften und Maschinenbau
Dokumentart : Journalartikel
Kurzfassung: Pure and doped niobium oxide (Nb2O5) layers are electrochromic (EC) materials which change their colour by insertion of Li+ ions from transparent to brown, grey or blue depending on the crystallinity of the layer. EC-devices with the configuration K-glass / EC-layer / composite electrolyte / Ion-storage (IS) layer / K-glass, were produced using different Nb2O5 EC-layers, a (CeO2)x(TiO2)1-x (x=0.45) IS-layer and an inorganic-organic composite electrolyte to which a small amount of water (up to 3 wt%) was added. The grey coloring all-solid-state sol-gel devices fabricated with Nb2O5:Mo coatings show a high reversible colouration (DeltaOD = 0.3) and a longterm stability of more than 55000 switching cycles. Large area EC-devices (30 cm x 40 cm) show a transmittance change between 60% and 25% at 550 nm after galvanostatic colouration and bleaching for 3 min and a colouration efficiency of 27 cm²/C. The results obtained with blue and brown colouring Nb2O5 EC-layers and a comparison with blue coloring WO3 layers are also presented.
Link zu diesem Datensatz: urn:nbn:de:bsz:291-scidok-25461
hdl:20.500.11880/24256
http://dx.doi.org/10.22028/D291-24200
SciDok-Publikation: 11-Nov-2009
Fakultät: Sonstige Einrichtungen
Fachrichtung: SE - INM Leibniz-Institut für Neue Materialien
Fakultät / Institution:INM
SE - Sonstige Einrichtungen

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