Please use this identifier to cite or link to this item: doi:10.22028/D291-23983
Title: Reactivity of a base-stabilized germanimine and germathione
Author(s): Veith, Michael
Detemple, Astrid
Language: English
Year of Publication: 1992
OPUS Source: Phosphorus, sulfur and silicon and the related elements. - 65. 1992, S. 17-24
SWD key words: Cycloaddition
DDC notations: 540 Chemistry
Publikation type: Journal Article
Abstract: After studying the reactivity of the base-stabilized germanimine (MeSi)2(NtBu)4Ge=NSiMe3 1 and germanethione (MeSi)2(NtBu)4Ge=S 2 towards simple polar molecules, we were interested in their cycloaddition chemistry. 1 gives no reaction with ketones (e. g. benzophenone) and dienes (e. g. 2,3-dimethylbutadiene). The reaction of 1 with an excess of CS2 gives 2 and trimethylsilylisothiocyanate 4. 2 reacts with the dichlorocarbene to give the bis(amino)dichlorogermane 5.
Link to this record: urn:nbn:de:bsz:291-scidok-19948
Date of registration: 23-Jan-2009
Faculty: SE - Sonstige Einrichtungen
Department: SE - INM Leibniz-Institut für Neue Materialien
NT - Chemie
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