Please use this identifier to cite or link to this item: doi:10.22028/D291-23877
Title: Photoelectron spectra and molecular properties. - L : On the blue color of bis(trimethylsilyl)diimine
Author(s): Bock, H.
Wittel, K.
Veith, Michael
Wiberg, Nils
Language: English
Year of Publication: 1976
OPUS Source: Journal of the American Chemical Society. - 98. 1976, 1, S. 109-114
SWD key words: Photoelektron
DDC notations: 540 Chemistry
Publikation type: Journal Article
Abstract: Photoelectron (PE) and uv spectra of group 4 azo compounds R3X-N=N-YR3 (X, Y = C, Si) and H5C6-N=N-XR3 (X = C, Si, Ge) are reported. A comparative discussion, based on CNDO calculations, attributes the low ionization potentials of the trimethylsilyl derivatives to substantial electron donation from the R3Si substituents. The unique electronic spectrum of the title compound can be rationalized considering in addition electron-electron interaction as well as Rydberg excitations.
Link to this record: urn:nbn:de:bsz:291-scidok-18795
Date of registration: 8-Dec-2008
Faculty: SE - Sonstige Einrichtungen
Department: SE - INM Leibniz-Institut für Neue Materialien
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