Please use this identifier to cite or link to this item: doi:10.22028/D291-23860
Title: Different reaction behavior of lead bis(tri-tert-butoxygermanate) and lead bis(tri-tert-butoxystannate) towards nonacarbonyldiiron [Chemistry of alkoxystannates ; 7]
Author(s): Veith, Michael
Hans, Johannes
Language: English
Year of Publication: 1991
OPUS Source: Angewandte Chemie / International edition in English. - 30. 1991, 7, S. 878-880
SWD key words: Germanium
DDC notations: 540 Chemistry
Publikation type: Journal Article
Abstract: The stereochemical activity of the lone pair on the Pb atom of 1 is dramatically increased when Fe(CO)4 units are attached to the Ge atoms to form 2. In 1 the Pb atom is completely surrounded by three tert-butoxy groups; in 3 this congestion is relieved and replaced by a chelatelike coordination through an O and an Fe atom. In contrast, the coordination sphere of the Pb atom in 3 remains intact on formation of the analogous Fe(CO)4 adduct.
Link to this record: urn:nbn:de:bsz:291-scidok-18379
Date of registration: 5-Dec-2008
Faculty: SE - Sonstige Einrichtungen
Department: SE - INM Leibniz-Institut für Neue Materialien
NT - Chemie
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