Please use this identifier to cite or link to this item: doi:10.22028/D291-23845
Title: Spektroskopischer Nachweis eines Bis(amino)silylens
Author(s): Veith, Michael
Werle, E.
Lisowsky, Richard
Köppe, Ralf
Schnöckel, Hansgeorg
Language: English
Year of Publication: 1992
OPUS Source: Chemische Berichte. - 125. 1992, 6, S. 1375-1377
SWD key words: Spektroskopie
DDC notations: 540 Chemistry
Publikation type: Journal Article
Abstract: The photolysis of the silicon diazide 3a in benzene solution and in an Ar matrix is described. Both irradiations cause the elimination of 3 equivalents of N2. Loss of N2 from 3a in benzene leads to the formation of the analytically investigated product or products 4 of uncertain structure. However, the matrix photolysis of 3a results in a compound which is stable up to 77 K and has been identified as the bis(amino)silylene 2 d by comparison of its IR spectra with those of the homologous Sn and Ge compond.
Link to this record: urn:nbn:de:bsz:291-scidok-18025
Date of registration: 4-Dec-2008
Faculty: SE - Sonstige Einrichtungen
Department: SE - INM Leibniz-Institut für Neue Materialien
NT - Chemie
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